Morrell, in handbook of environmental degradation of materials second edition, 2012 14. The traditional soxhlet extraction of pentachlorophenol pcp from. Pentachlorophenol solution analytical standards 87865. Now the time has come to put your hand in your pocket and help us to maintain this wonderful solution. It can be found as pure pcp, or as the sodium salt of pcp, the latter of which dissolves easily in water. This usually appears as blackheads, whiteheads and yellow cysts over the temples and around the ears. Ntp c 2014 the commercially available complex mixture of pentachlorophenol and byproducts of its synthesis is a restricteduse pesticide and registered as a heavyduty wood preservative for utility poles, cross arms, pilings, fence posts, and construction. Transfer pumps are used to remove solution from the treatment vessel and transfer it to the.
The 2008 health risk limit hrl for pentachlorophenol 1. Each of 2 rabbits was given 1 oral dose of sodium salt 0. Pentachlorophenol 87865, and pentachlorophenol, sodium salt 1522 cancer. Pentachlorophenol pcp is a pesticide and disinfectant that is used industrially as a wood preservative. Pentachlorophenol is extremely toxic to humans from acute shortterm ingestion and. Skin potential significant contribution to overall exposure by the cutaneous r oute 0.
Pentachlorophenol 87865 hazard summary pentachlorophenol was once one of the most widely used biocides in the united states, but it is now a restricted use pesticide and is no longer available to the general public. Pentachlorophenol sodium salt hydrate 90% cas number 123333540. Pocket guide to chemical hazards pentachlorophenol cas 87865 can be absorbed through the skin. A 1984 report cites the measured concentration of pentachlorophenol in the indoor air of pressuretreated log homes brushed with pentachlorophenol in the range of 0. Download free inchi key software synthetic cannabinoid. Pentachlorophenol pressure treated wood stella jones.
Pdf determination of pentachlorophenol in drinking water. These two forms have some different physical properties, but are expected to have similar toxic effects. Pentachlorophenol or penta was developed in the 1930s as one of the first synthetic organic wood preservatives. Watch this space global msds ltds is making its database of chemical regulations available to everyone completely free. Cytidine5phosphate36aminohexylphosphate, labeled with cy3, triethylammonium salt. Safety and health manual osha archive document notice. First produced in the 1930s, it is marketed under many trade names. At one point, penta was the most widely used preservative but concerns. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and.
Buy pentachlorophenol sodium salt cas 1522, a product for proteomics research, from santa cruz. Once the skin is free of the wood dust, wash thoroughly with soap and water. Material safety data sheet pentachlorophenol msds section 1. Adobe acrobat reader dc software is the free global standard for reliably viewing, printing, and commenting on pdf documents. We use cookies to ensure that we give you the best experience of our website. Buy high purity pentachlorophenol analytical standards from chem service inc. Sep 23, 2003 material safety data sheet pentachlorophenol treated wood section 1 identification manufacturers name. All mass spectra in this site plus many more are available from the nistepanih mass spectral library. Chemical product and company identification product name. Pentachlorophenol and drinking water pentachlorophenol pcp is a contaminant that has been found in waters that could be used as drinking water sources in minnesota. May 19, 20 pentachlorophenol is an organochlorine compound, which is a white needlelike crystal. How effective is persulfox in treating pentachlorophenol. Pentachlorophenol c6cl5oh or c6hcl5o cid 992 structure, chemical names, physical and chemical properties, classification, patents, literature, biological. Pentachlorophenol has been found to have toxic effects in laboratory animals.
May 21, 20 material safety data sheet pentachlorophenol msds section 1. Material safety data sheet pentachlorophenol treated. Pentachlorophenol pcp is a synthetic substance that was first produced in the 1930s. Pentachlorophenol an overview sciencedirect topics. Pentachlorophenol cas 87865 can be absorbed through the skin. This is an osha archive document and may no longer represent osha policy. Pentachlorophenol pcp is an organochlorine compound used as a pesticide and a disinfectant. Aderco 2055g safety data sheet download msds ghsclp. Pham, in encyclopedia of toxicology third edition, 2014 background. Report msds natrium hidroksida please fill this form, we will try to respond as soon as. Included here are those ionophores that disrupt electron transfer by.
Material safety data sheets msds for products such as preservatives and treated wood. Pentachlorophenol, abbreviated to pcp, is registered with cas number 87 86 5. Material safety data sheet pentachlorophenol treated wood section 1 identification manufacturers name. Pcp has been used as an herbicide, algaecide, defoliant, wood preservative, germicide, fungicide and molluskacide. To see more msds documents from our industryleading safety data sheet sds database use our msds search tool. Surface area effects in mass transfer or heterogeneous reactions. Buy high purity pentachlorophenol solution analytical standards from chem service inc. Pentachlorophenol is a chlorinated aromatic compound that has been used extensively as a fungicide.
Pcp is a synthetic substance, made from other chemicals, and does not occur. Toxic and hazardous industrial chemicals safety manual. Pentachlorophenol pressure treated wood is treated with a restricted use. Adhere to everchanging regulations with our pentachlorophenol reference standards for environmental testing, cas number. The use of company or product names is for identification only and does not imply endorsement by the agency for toxic substances and disease registry. Methods for estimation of preservatives in treated. Pentachlorophenol c6cl 5oh is an aroma tic hydrocarbon of the chlorophenol family. Determination of pentachlorophenol residue in meat and fish. Overexposure to pentachlorophenol could result in injury, illness, or even possibly death. Pentachlorophenolpcp california department of pesticide. Recommendations for the design and operation of wood. Start free trial unlimited sds searches, 5 free downloads, no credit card instant free trial. For both pentachlorophenol and tetrachlorohydroquinone, sulfates accounted for 90% or more of the total conjugates. Since itsintroduction pcp has had a variety of other applicat ions.
Pcp exposure doses in the ntp 30day subchronic toxicity study in. The milliq water was obtained from millipore system. Exposure to treated wood should be kept to a minimum. How effective is persulfox in treating pentachlorophenol pcp. By federal law, manufacturers must supply this info in an msds which we provide here, free. Please see the following for information about the library and its accompanying search program. In order to promote public education and public safety, equal justice for all, a better informed citizenry, the rule of law, world trade and world peace, this legal document is hereby made available on a noncommercial basis, as it is the right of all humans to know and speak the laws that govern them. The minnesota department of health mdh developed a healthbased guidance value for pcp in drinking water and, based on this value, does not expect levels of pcp in. Pentachlorophenol is readily absorbed through the skin, causing irritation. It is marketed under the trade names, santophen, pentachlorol, chlorophen, chlon, dowicide 7, pentacon, penwar, sinituho and penta among others. It can be biodegraded by some bacteria, including sphingobium chlorophenolicum. Download free adobe acrobat reader dc software for your windows, mac os and android devices to view, print, and comment on pdf documents.
Cdc niosh pocket guide to chemical hazards pentachlorophenol. To find out how you can continue to use this service as paid subscriber, please click the button below. Chapter e pentachlorophenol pressure pcpp wood preservation facilities. The hplcgrade methanol 99,9% was purchased from carlo erba reagents and hplcgrade acetonitrile 98%, formic acid 98%, phosphoric acid 85%, ammonium acetate 98% and sodium. This instruction establishes a safety and health management system shms for occupational safety and health administration osha.
Pcp, penta, 2,3,4,5,6 pentachlorophenol colorless to white, crystalline solid with a benzenelike odor. Determination of pentachlorophenol residue in meat and. Prolonged exposure can cause reversible corneal damage. Only treated wood that is visibly clean and free of sur. Do not use this product until the msds has been read and understood. Monooxygenase activity was markedly induced by technical grade pentachlorophenol in a concn dependent pattern, with a maximum response of approx 14 fold seen at. Pcp was first introduced for use as wood preservative in the 1930s.
Possible cancer hazard may cause cancer based on animal data. Formerly known as material safety data sheets, phac now refers to them as pathogen safety data sheets or psdss. The most complete free material safety data sheet msds list. Pentachlorophenol c6cl5oh or c6hcl5o cid 992 structure, chemical. Public health goal for pentachlorophenol in drinking water. Osha table z1 limits for air contaminants 29 cfr 1910.
Penta is highly effective against fungi and insects but not against marine borers. Risk assessment and hazard evaluation activities relating to chemical contaminants in drinking water. And now, its connected to the adobe document cloud. Only treated wood that is visibly clean and free of surface residue should be used for patios, decks and. Links and downloads related to proposition 65 statute and regulations. Free msds documents for known infectious diseases provided as a public service through health canada. Epidemiological studies of workers in the wood treating industry have shown no significant health effects due to occupational exposure to pentachlorophenol preservative. Here is the most complete msds list on the internet, and its free. A portion of the dose was recovered in urine as tetrachlorohydroquinone 5% and its conjugates 15%. Do not rub until skin is free of sawdust and preservative material.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Pentachlorophenol was primarily recovered in urine as glucuronide and sulfate conjugate metabolites. New healthbased values hbvs, including noncancer values, were drafted in 20. In addition to free pentachlorophenol, rats excrete tetrachlorophydroquinone and trichlorophydroquinone. The solubility of pentachlorophenol pcp is 35 mgl in water at 50c. Pentachlorophenol pcp is a pesticide and disinfectant that is used industrially as a wood preservative pcp is an environmental and health concern due to its bioaccumulation and potential carcinogenic properties it is desirable to treat pcp in soil and groundwater using costeffective in situ technologies such as bioremediation, oxidation, or reduction. Pentachlorophenol pressure treated woodpolespiling.
Looking for msds information regarding the chemicals in a commercial product or a material safety data sheet msds. Weve given you 5 free safety data sheets that well look after for you moving forward. These values were adopted into rule as hrls n november 2015. Material safety data sheet fuel oil has been shown to produce tumor formation in laboratory animals following longterm application. Hepatocytes isolated from adult sprague dawley rats were incubated with analytical pentachlorophenol of 99% purity, technical grade pentachlorophenol, or its sodium salt, whic contains only minor concn of technical impurities. Empirical formula hill notation c 6 cl 5 nao xh 2 o. From the 1950s to the late 1980s pentachlorophenol based fungicides were widely used in the new zealand sawmill industry, and there were persistent claims of longterm adverse effects on health. Download product insert pdfdownload gcms pdfdownload safety data sheet sds pdf. Pcp itself or as the sodium salt of pcp, which dissolves easily in water. United nations stockholm convention on persistent organic. Material safety data sheet pentachlorophenol 62899 page 2 of 7 chloracne in humans, the absorption of pentachlorophenol by any route may result in the development of the skin condition, chloracne. Material safety data sheet pentachlorophenol treated wood. Intent to list pentachlorophenol and byproducts of its. Download fulltext pdf download fulltext pdf read fulltext.
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